ESR study of exchange coupled pairs in copper diethyldithiocarbamate—explanation of the low temperature hyperfine anomaly

A study of the hyperfine interaction in the ESR of Cu-Cu pairs in single crystals of copper diethyldithiocarbamate as a function of temperature has shown distinct differences in the hyperfine structure in the two fine structure transitions at 20 K, the spectrum not having the same hyperfine intensity pattern in the low field fine structure transition in contrast to that of the high field transition. The details of the structure of both the fine structure transitions in the 20 K spectrum have now been explained by recognizing the fact that the mixing of the nuclear spin states caused by the anisotropic hyperfine interaction affects the electron spin states | + 1 > and | −> differently. This has incidentally led to a determination of the sign ofD confirming the earlier model. The anomalous hyperfine structure is found to become symmetric at 77 K and 300 K. It is proposed that the reason for this lies in the dynamics of spin-lattice interaction which limits the lifetime of the spin states in each of the electronic levels | − 1 >, | 0 > and | + 1 > The estimate of spin-lattice relaxation time agrees with those indicated from other studies. The model proposed here for the hyperfine interaction of pairs in the electronic triplet state is of general validity.     

Evaluation of the Intensities of Spectral Lines under the Influence of Interferences and the Determination of Global Maxima of the Mass–Spectrum Peaks

We describe the technique by which the intensity of spectral lines can be evaluated and the global maxima of the mass–spectrum peaks under the influence of pulse interferences can be defined using an experimental setup based on a commercial MX–7304A mass spectrometer, IBM personal computer (PC), and a digital extremum regulator that allows one to ignore local extrema and bring about automatic search for a global maximum of the mass–spectrum peak and its tracking with an accuracy of 0.0012% at a speed of response of 50 kHz, elevated speeds of the scanning of masses 500 amu/sec, and stability of regulation.     

The low<Subscript><Emphasis Type="Italic">n</Emphasis></Subscript> and low<Subscript><Emphasis Type="Italic">m</Emphasis></Subscript> r. e. degrees are not elementarily equivalent

Jockusch, Li and Yang showed that the Lown and Low1 r.e. degrees are not elementarily equivalent for n > 1. We answer a question they raise by using the results of Nies, Shore and Slaman to show that the Lown and Lowm r.e. degrees are not elementarily equivalent for n > m > 1.     

Transition Probabilities for Symmetric Jump Processes

We consider symmetric Markov chains on the integer lattice in dimensions, where and the conductance between and is comparable to . We establish upper and lower bounds for the transition probabilities that are sharp up to constants.

     

Temporal Difference Methods for the Maximal Solution of Discrete-Time Coupled Algebraic Riccati Equations

In this paper, we present an iterative technique for deriving the maximal solution of a set of discrete-time coupled algebraic Riccati equations, based on temporal difference methods, which are related to the optimal control of Markovian jump linear systems and have been studied extensively over the last few years. We trace a parallel with the theory of temporal difference algorithms for Markovian decision processes to develop a -policy iteration like algorithm for the maximal solution of these equations. For the special cases in which =0 and =1, we have the situation in which the algorithm reduces to the iterations of the Riccati difference equations (value iteration) and quasilinearization method (policy iteration), respectively. The advantage of the proposed method is that an appropriate choice of between 0 and 1 can speed up the convergence of the policy evaluation step of the policy iteration method by using value iteration.     

Effect of the compliant interlayer on the dynamic stress intensity factor in a piecewise-homogeneous solid with a circular crack

The dynamic behavior of a circular crack in an elastic composite consisting of two dissimilar half-spaces connected by a thin compliant interlayer is studied. One half-space contains a defect aligned perpendicular to the interlayer; the defect surfaces are loaded by normal harmonic forces, which ensures the symmetry of the stress-strain state. The thin interlayer is modeled by conditions of a nonideal contact of the half-spaces. The problem is reduced to a boundary integral equation with respect to the function of dynamic opening of the defect. The numerical solution of this equation yields frequency dependences of the mode I stress intensity factor in the vicinity of the crack for different values of interlayer thickness and relations between the moduli of elasticity of the composite components. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 49, No. 3, pp. 197–207, May–June, 2008.     

Determination of mixed-mode stress intensity factors, fracture toughness, and crack turning angle for anisotropic foam material

A numerical and experimental investigation for determining mixed-mode stress intensity factors, fracture toughness, and crack turning angle for BX-265 foam insulation material, used by NASA to insulate the external tank (ET) for the space shuttle, is presented. BX-265 foam is a type of spray-on foam insulation (SOFI), similar to the material used to insulate attics in residential construction. This cellular material is a good insulator and is very lightweight. Breakup of segments of this foam insulation on the shuttle ET impacting the shuttle thermal protection tiles during liftoff is believed to have caused the space shuttle Columbia failure during re-entry. NASA engineers are interested in understanding the processes that govern the breakup/fracture of this material from the shuttle ET. The foam is anisotropic in nature and the required stress and fracture mechanics analysis must include the effects of the direction dependence on material properties. Material testing at NASA Marshall Space Flight Center (MSFC) has indicated that the foam can be modeled as a transversely isotropic material. As a first step toward understanding the fracture mechanics of this material, we present a general theoretical and numerical framework for computing stress intensity factors (SIFs), under mixed-mode loading conditions, taking into account the material anisotropy. We present SIFs for middle tension – M(T) – test specimens, using 3D finite element stress analysis (ANSYS) and FRANC3D fracture analysis software. SIF values are presented for a range of foam material orientations. Mode I fracture toughness of the material is determined based on the SIF value at failure load. We also present crack turning angles for anisotropic foam material under mixed-mode loading. The results represent a quantitative basis for evaluating the strength and fracture properties of anisotropic foam insulation material.     

Stress state of a piezoceramic body with a plane crack opened by a rigid inclusion

The paper establishes a relationship between the solutions for cracks located in the isotropy plane of a transversely isotropic piezoceramic medium and opened (without friction) by rigid inclusions and the solutions for cracks in a purely elastic medium. This makes it possible to calculate the stress intensity factor (SIF) for cracks in an electroelastic medium from the SIF for an elastic isotropic material, without the need to solve the electroelastic problem. The use of the approach is exemplified by a penny-shaped crack opened by either a disk-shaped rigid inclusion of constant thickness or a rigid oblate spheroidal inclusion in an electroelastic medium __________ Translated from Prikladnaya Mekhanika, Vol. 44, No. 7, pp. 47–60, July 2008.     

Elastic state of a transversely isotropic piezoelectric body with an arbitrarily oriented elliptic crack

The elastic stress state in a piezoelectric body with an arbitrarily oriented elliptic crack under mechanical and electric loads is analyzed. The solution is obtained using triple Fourier transform and the Fourier-transformed Green’s function for an unbounded piezoelastic body. Solving the problem for the case of a crack lying in the isotropy plane, for which there is an exact solution, demonstrates that the approach is highly efficient. The distribution of the stress intensity factors along the front of a crack in a piezoelectric body under uniform mechanical loading is analyzed numerically for different orientations of the crack __________ Translated from Prikladnaya Mekhanika, Vol. 44, No. 2, pp. 39–48, February 2008.     

Variation of the stress intensity factor along the crack front of interacting semi-elliptical surface cracks

Summary  In this study, the interaction between two semi-elliptical co-planar surface cracks is considered when Poisson's ratio ν = 0.3. The problem is formulated as a system of singular integral equations, based on the idea of the body force method. In the numerical calculation, the unknown density of body force density is approximated by the product of a fundamental density function and a polynomial. The results show that the present method yields smooth variations of stress intensity factors along the crack front very accurately, for various geometrical conditions. When the size of crack 1 is larger than the size of crack 2, the maximum stress intensity factor appears at a certain point, β₁=177^∘, of crack 1. Along the outside of crack 1, that is at β₁=0∼90^∘, the interaction can be negligible even if the two cracks are very close. The interaction can be negligible when the two cracks are spaced in such a manner that their two closest points are separated by a distance exceeding the small crack's major diameter. The variations of stress intensity factor of a semi-elliptical crack are tabulated and charted. Received 30 August 1999; accepted for publication 22 February 2000